M. D. Ward Group
Chemical Engineering & Materials Science
University of Minnesota - Twin Cities
Crystal Growth and Design

Publications

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158. "Hydrogen-bonded host frameworks with tunable cavities: structural characterization and inclusion-based separations of molecular isomers", M. J. Horner, S. Grabowski, K. Sandstrom, K. T. Holman, M. Bader, M. D. Ward, W.-S. Kim, ACA Transactions 2004, 39, 130.

157. "Dynamic behavior of particle agglomeration of europium oxalate during reaction crystallization in semi-batch reactor", W.-S. Kim, W.-S. Kim, K.-S. Kim, J.-S. Kim, T. Jung, and M. D. Ward, Chem. Eng. Commun. 2006, 193, 370.

156. "Design of Crystalline Molecular Networks with Charge-Assisted Hydrogen Bonds", M. D. Ward, Chem. Commun. 2005, 5838.

155. "Directing the Assembly of Molecular Crystals", M. D. Ward, MRS Bulletin 2005, 30, 705.

154. "Chiral Discrimination in Low-Density Hydrogen-Bonded Frameworks", R. Custelcean, and M. D. Ward, Cryst. Growth Des. 2005, 5, 2277.

153. "Crystal Surface Adhesion Explains the Pathological Activity of Calcium Oxalate Hydrates in Kidney Stone Formation", X. Sheng, M. D. Ward and J. A. Wesson, J. Am. Soc. Nephrol 2005, 16, 1904.

152. "Snapshots of Crystal Growth", M. D. Ward, Science (Perspectives) 2005, 308, 1566.

151. "Lyotropic Phases Reinforced by Hydrogen Bonding", S. M. Martin, and M. D. Ward, Langmuir 2005, 21, 5324.

150. "Structural Transference and Regulation of Bimodal Assembly of Charge-Assisted Hydrogen-Bonded Networks", S.-O. Lee, D. M. Shacklady, M. J. Horner, S. Ferlay, M. W. Hosseini, and M. D. Ward, Cryst. Growth Des. 2005, 5, 995.

149. "Thermotropic Properties of Organic Nanocrystals Embedded in Ultrasmall Crystallization Chambers", J.-M. Ha, M. A. Hillmyer, and M. D. Ward, J. Phys. Chem. B, 2005, 109, 1392.

148. "Adhesion at calcium oxalate crystal surfaces and the effect of urinary constituents", X. Sheng, T. Jung, J. A. Wessen, and M. D. Ward, Proc. Natl. Acad. Sci. USA, 2005, 102, 267. 

147. "Structure and order in soft matter: symmetry transcending length scale", M. D. Ward, and M. J. Horner, Cryst. Eng. Comm., 2004, 6, 401. 

146. "Probing crystallization of calcium oxalate monohydrate and the role of macromolecule additives with in situ atomic force microscopy", T. Jung, X. Sheng, C. K. Choi, W.-S. Kim, J. A. Wesson, and M. D. Ward, Langmuir, 2004, 20, 8587.

145. "Rheology and morphology of smectic liquid crystal/polymer blends", J. Yonezawa, S. M. Martin, C. W. Macosko, and M. D. Ward, Macromolecules 2004, 37, 6424.

144. "Structure and rheology of hydrogen bond reinforced liquid crystals", S. M. Martin, J. Yonezawa, M. J. Horner, C. W. Macosko, and M. D. Ward, Chem. Mater., 2004, 16, 3045.

143. "Organic thin-film transistors based on tolyl-substituted oligothiophenes", S. Mohapatra, B. T. Holmes, C. R. Newman, C. F. Prendergast, C. D. Frisbie, and M. D. Ward, Adv. Func. Mater., 2004, 14, 605.

142. "Structural Characterization of a Pentacene Monolayer on an Amorphous SiO2 Substrate with Grazing Incidence X-ray Diffraction", S. E. Fritz, S. M. Martin, C. D. Frisbie, M. D. Ward, and M. F. Toney, J. Am. Chem. Soc., 2004, 126, 4084.

141. "Polymorph Selectivity under Nanoscopic Confinement", J.-M. Ha, J. H. Wolf, M. A. Hillmyer, and M. D. Ward, J. Am. Chem. Soc., 2004, 126, 3382.

140. "Crystal Agglomeration of Europium Oxalate in Reaction Crystallization Using Double-Jet Semi-Batch Reactor", W.-S. Kim, W.-S. Kim, K.-S. Kim, J.-S. Kim, and M. D. Ward, Mater. Res. Bull., 2004, 39, 283.

139. "Two-Dimensional Host-Guest Inclusion Crystals at the Air-Water Interface", D. J. Plaut, S. M. Martin, K. Kjaer, M. J. Weygand , M. Lahav, L. Leiserowitz, I. Weissbuch and M. D. Ward, J. Am. Chem. Soc., 2003, 125, 15922-15934.

138. "Molecular Fuel Tanks", M. D. Ward, Science (Perspectives), 2003, 300, 1104.

137. "Study of the (001) Cleavage Planes of Guanidinium Methanesulfonate Single Crystals by AFM and He Diffraction", G. Bracco, Y. Hu, J. Acker, and M. D. Ward, Appl. Surf. Sci. , 2003, 212-213, 151.

136. "Atomic Diffraction Study of the Interaction of Helium Atoms with the Surface of an Organic Single Crystal: the (001) Cleavage Planes of Guanidinium Methanesulfonate", G. Bracco, J. Acker, M. D. Ward, and G. Scoles, J. Chem. Phys., 2003, 118, 8405. [Selected for the May 5, 2003 issue of the Virtual Journal of Nanoscale Science and Technology; http://www.vjnano.org]

135. "Tricyanovinyl-Substituted Oligothiophenes", M. M. Bader, R. Custelcean, M. D. Ward, Chem. Mater. 2003; 15, 616.

134. "Adhesion between Molecules and Calcium Oxalate Crystals: Critical Interactions in Kidney Stone Formation", X. Sheng, M. D. Ward, and J. A. Wesson, J. Am. Chem. Soc., 2003, 125, 2854. [Highlighted in Nature, 2003, 422, 275].

133. "Helium Diffraction Study of Polar and Non-Polar (001) Surfaces of a Layered Hydrogen-bonded Crystal", G. Bracco, J. Acker, M. D. Ward, and G. Scoles, Langmuir, 2002, 18, 5551.

132. "Hydrogen-bonded Helices in Crystals with Prescribed Organization", R. Custelcean and M. D. Ward, Angew. Chem. Int. Ed. 2002, 41, 1724.

131. "Direct Visualization of Calcium Oxalate Monohydrate (COM) Crystallization and Dissolution with Atomic Force Microscopy (AFM) and the Role of Polymeric Additives", Shouwu Guo, Michael D. Ward, and Jeffrey A. Wesson, Langmuir 2002, 18, 4284.

130. "Probing Vibrational Dynamics of Hydrogen-bonded Inclusion Compounds with Inelastic Neutron Scattering and ab initio Calculations", A. M. Pivovar, M. D. Ward, C. M. Brown, and D. A. Neumann, J. Phys. Chem. B, 2002, 106, 4916.

129. "Engineering Space Group Symmetry and Polar Order in Molecular Host Frameworks", K. T. Holman, A. M. Pivovar, M. D. Ward, Science 2001, 294, 1907.

128. "Lamellae-Nanotube Isomerism in Hydrogen-Bonded Host Frameworks", M. J. Horner, K. T. Holman, M. D. Ward, Angew. Chem. Int. Ed. 2001, 40, 4045.

127. "Shape Selective Separation of Molecular Isomers with Tunable Hydrogen-bonded Host Frameworks", A. M. Pivovar, K. T. Holman and Michael D. Ward, Chem. Mater. 2001, 13, 3018.

126. "Vibrational Mode Analysis of Isomorphous Hydrogen-Bonded Guanidinium Sulfonates with Inelastic Neutron Scattering and Density Functional Theory", A. M. Pivovar, M. D. Ward, T. Yildirim, D. A. Neumann, J. Chem. Phys., 2001, 115, 1909.

125. "Electrochemical Growth of Epitaxial Organic Films", M. D. Ward, Encyclopedia of Electrochemistry, Volume 10, “Modified Electrodes”

124. "Selective Nucleation and Discovery of Organic Polymorphs through Epitaxy with Organic Single Crystal Substrates", C. Mitchell, L. Yu, and M. D. Ward, J. Am. Chem. Soc, 2001, 123, 10830.

123. "The Generality of Architectural Isomerism in Designer Inclusion Frameworks", K. T, Holman, S. M. Martin, D. P. Parker and M. D. Ward, J. Am. Chem. Soc. 2001, 123, 4421.

122. "Epitaxy and Molecular Organization on Solid Substrates", D. E. Hooks, T. Fritz and M. D. Ward, Adv. Mater. 2001, 13, 227.

121. "Metric Engineering of Soft Molecular Host Frameworks", K. T. Holman, A. M. Pivovar, J. A. Swift and M. D. Ward, invited article, Acc. Chem. Res., 2001, 34, 107.

120. "Bulk Crystals to Surfaces: Combining X-ray Diffraction and Atomic Force Microscopy to Probe the Structure and Formation of Crystal Interfaces", M. D. Ward, Chem. Rev., 2001, 101, 1697.

119. "Plastic Sandwiches `a la carte", M. D. Ward, Nature (News and Views), 2000, 405, 293.

118. "Building Molecular Frameworks with Tailored Pore Structures", D. J. Plaut, K. T. Holman, A. M. Pivovar and M. D. Ward, J. Phys. Org. Chem. Special Issue “Materials for the 21st Century,” 2000, 13, 858.

117. "Crystal Engineering with Soft and Topologically Adaptable Molecular Host Frameworks", K. T. Holman and M. D. Ward, Stimulating Concepts in Chemistry, Vogtle, Stoddart, and Shibasaki, Eds., Wiley-VCH, Weinheim, 2000, p221.

116. "Metric Engineering of Crystalline Inclusion Compounds by Structural Mimicry", K. T. Holman and M. D. Ward, Angew. Chem. Int. Ed. Engl., 2000, 39, 1653.

115. "Low-density hydrogen-bonded networks in crystals and at the air-water interface", D. J. Plaut, K. M. Lund, and M. D. Ward, Chem. Comm., 2000, 769.

114. "Cooperative Polar Ordering in Topologically Constrained Crystalline Inclusion Compounds", J. A. Swift and M. D. Ward, Chem. Mater. 2000, 12, 1501.

113. "Control of Hierarchical Order in Crystalline Composites of Diblock Copolymers and a Molecular Chromophore", C. C. Evans, F. S. Bates, and M. D. Ward, Chem. Mater. 2000, 12, 236.

112. "Structural Studies of a Crystalline Insulin Analog Complex with Protamine by Atomic Force Microscopy", C. M Yip, M. L. Brader, B. H. Frank, M. R. DeFelippis and M. D. Ward, Biophys. J., 2000, 78, 466.

111. "Electrochemical Quartz Crystal Microbalance", M. D. Ward, Encyclopedia of Analytical Chemistry, R. A. Meyers, Ed., John Wiley & Sons, Chichester, 9930 – 9958, 2000.

110. "Self-Assembly of Crystalline Lattices", M. D. Ward and A. M. Pivovar, The Encyclopedia of Materials Science and Technology, 2nd edition, 1999.

109. "Organic Host-Guest Molecular Assemblies", M. D. Ward and A. M. Pivovar, Current Opinion in Solid state and Materials Science, 1999, 4, 581.

108. "Automated Electrochemical Analysis with Combinatorial Electrode Arrays", M. G. Sullivan, H. Utomo, P. J. Fagan and M. D. Ward, Anal. Chem., 1999; 71, 4369.

107. "The Physicochemical Origins of Coincident Epitaxy in Molecular Overlayers: Lattice Modeling vs. Potential Energy Calculations", J. A. Last, D. E. Hooks, A. C. Hillier and M. D. Ward, J. Phys. Chem. B, 1999, 103, 6723.

106. "Steric Control of Architectural Isomerism in Hydrogen Bonded Crystalline Clathrates", C. C. Evans, L. Sukarto and M. D. Ward, J. Am. Chem. Soc., 1999, 121, 320.

105. "Surfactant Enhanced Spreading", T. Stoebe, R. M. Hill, M. D. Ward, L. E. Scriven and H. T. Davis, "Silicone Surfactants," Surfactant Science Series, Vol. 86, R. M. Hill, Ed.; Marcel Dekker, New York, 1999.

104. "Chemistry on the Edge: A Microscopic Analysis of the Intercalation, Exfoliation, Edge Functionalization, and Monolayer Surfacing Tiling Reactions of a-Zirconium Phosphate", D. M. Kaschak, S. A. Johnson, D. E. Hooks, H.-N. Kim, M. D. Ward, T. E. Mallouk, J. Am. Chem. Soc. 1998, 120, 10887.

103. "Cooperative Host-Guest Recognition in Crystalline Clathrates: Steric Guest Ordering by Molecular Gears", J. A. Swift, A. M. Reynolds and M. D. Ward, Chem. Mater., 1998, 10, 4159.

102. "Nanoconfined Electrochemical Nucleation of Crystalline Molecular Monolayers on Graphite Substrates", D. E. Hooks, C. M. Yip, and M. D. Ward, J. Phys. Chem. B. 1998, 102, 9958.

101. "Molecular Scaffolds", M. D. Ward, Chem. Brit., 1998, 34, 52.

100. "Structural and Morphological Characterization of Ultralente Insulin Crystals by Atomic Force Microscopy:Evidence of Hydrophobically Driven Assembly", C. M. Yip, M. R. DeFelippis, B. H. Frank, M. L. Brader and M. D. Ward, Biophys. J., 1998, 75, 1172.

99. "Template Induced Architectural Isomerism in Porous Molecular Lattices: Engineering of Crystalline Clathrates", J. A. Swift, A.M. Pivovar, and A. M. Reynolds, J. Am. Chem. Soc., 1998, 120, 5887.

98. "Direct Force Measurements of Insulin Monomer-Monomer Interaction Forces", C. M. Yip, C. C. Yip and M. D. Ward, Biochem. 1998, 37, 5439.

97. "Atomic Force Microscopy of Crystalline Insulins: The Influence of Sequence Variation on Crystallization and Interfacial Structure", C. M. Yip, M. L. Brader, M. R. DeFelippis and M. D. Ward, Biophys. J. 1998, 74, 2199.

96. "Interweaving of Two-Dimensional Hydrogen-Bonded Networks Directed by Chloride Ions", V. A. Russell and M.D. Ward, New J. Chem., Special Issue on Supramolecular Chemistry, 1998, 22, 149.

95. "Epitaxially-Driven Assembly of Crystalline Molecular Films on Ordered Substrates", J. A. Last, A. C. Hillier, D. E. Hooks, J. B. Maxson, and M. D. Ward, Chem. Mater., 1998, 10, 422.

94. "Structure and Physical Properties of Hexacyanomanganate(IV), [MnIV(CN)6]2-", W. E. Buschmann, C. Vazquez, R. S. McLean, M. D. Ward, N. L. Jones, J. S. Miller, J. Chem. Soc. Chem. Commun. 1997, 409. 

93. "Organoporous Hosts with Adjustable Molecular Environments", J. A. Swift, V. A. Russell and M. D. Ward, Adv. Mater. 1997, 9, 15.

92. "Superspreading of Aqueous Films Containing Trisiloxane Surfactant on Mineral Oil", T. Stoebe, Z. Lin, R. M. Hill, M. D. Ward and H. Ted Davis, Langmuir 1997, 13, 7282.

91. "Enhanced Spreading of Aqueous Films Containing Ionic Surfactants on Solid Substrates", T. Stoebe, R. M. Hill, M. D. Ward, and H. Ted Davis, Langmuir, 1997, 13, 7276.

90. "Enhanced Spreading of Aqueous Ethoxylated Alcohol Surfactant Systems on Solid Substrates", T. Stoebe, Z. Lin, R. M. Hill, M. D. Ward, and H. Ted Davis, Langmuir 1997, 13, 7270.

89. "Two-Dimensional Hydrogen-Bonded Assemblies: The Influence of Steric Effects and Competitive Hydrogen Bonding on the Structures of Guanidinium Arenesulfonate Networks", V. A. Russell and M.D. Ward, J. Mater. Chem. "Special Issue on Molecular Assemblies and Nanostructures," 1997, 7, 1123.

88. "Nanoporous Molecular Sandwiches: Pillared Two-Dimensional Hydrogen-Bonded Networks with Adjustable Porosity", V. A. Russell, C. Evans, W. Li and M. D. Ward, Science, 1997, 276, 575.

87. "Nanoscale Visualization of Crystal Habit Modification by Atomic Force Microscopy", G. Mao, L. Lobo, R. Scaringe and M. D. Ward, Chem. Mater. 1997, 9, 773.

86. "Organic Crystal Surfaces: Structure, Properties and Reactivity", M. D. Ward, Current Opinion in Colloid and Interfacial Science, 1997, 2, 51.

85. "Nucleation of Molecular Crystals at Guanidinium Alkylsulfonate Langmuir Monolayers", L. M. Frostman and M. D. Ward, Langmuir, 1997, 13, 330.

84. "Epitaxial Interactions between Organic Overlayers and Ordered Substrates", A. C. Hillier and M. D. Ward, Phys. Rev. B, 1996, 54, 14037.

83. "Probing Solvent Dynamics in Concentrated Polymer Films with a High Frequency Shear Mode Quartz Resonator", A. Katz and M . D. Ward, J. Appl. Phys., 1996, 80, 4153.

82. "Electrochemical Annealing of Domains in Epitaxial Molecular Films", J. A. Last and M. D. Ward, Adv. Mater., 1996, 8, 730.

81. "Atomic Force Microscopy of Insulin Single Crystals: Direct Visualization of Molecules and Crystal Growth", C. M. Yip and M. D. Ward, Biophys. J. 1996, 71, 1071.

80. "Molecular Crystals with Dimensionally Controlled Hydrogen-Bonded Nanostructures", V. A. Russell and M. D. Ward, Chem. Mater., 1996, 8, 1654.

79. "Determination of Contact Angles and Surface Tensions with the Quartz Crystal Microbalance", Z. Lin and M. D. Ward, Anal. Chem. 1996, 68, 1285.

78. "Surfactant Enhanced Spreading", T. Stoebe, Zuxuan Lin, Randal M. Hill, H. Ted Davis, and M. D. Ward, Langmuir, 1996, 12, 337.

77. "Improved Accuracy in Dynamic Quartz Crystal Microbalance Measurements of Surfactant Enhanced Spreading", Z. Lin, T. Stoebe, R. M. Hill, H. T. Davis, and Michael D. Ward, Langmuir, 1996, 12, 345.

76. "Scanning Tunneling and Atomic Force Microscopy of Electrochemical Interfaces (Invited Book Chapter)", M. D. Ward and H. S. White, Modern Techniques in Electroanalysis, Petr Vanysek, Ed.; Volume 139, Wiley (New York), 1996, p 107.

75. "Solid-State Structure of a Layered Hydrogen-Bonded Salt: Guanidinium 5-Benzoyl-4-Hydroxy-2-Methoxybenzenesulfonate Methanol Solvate", V. A. Russell and M. D. Ward, Acta Cryst., 1996, B52, 209-214.

74. "Structural and Physical Properties of Delocalized Mixed-Valent [Cp*M(pentalene)M’Cp*]n+ and [Cp*M(indacene)M’Cp*]n+ (M,M’ = Fe, Co, Ni; n = 0, 1, 2) Complexes", J. M. Manriquez, M. D. Ward, W. M. Reiff, J. C. Calabrese, N. L. Jones, P. J. Carroll, E. E. Bunel, J. S. Miller, J. Am. Chem. Soc. 1995, 117, 6182.

73. "Selective Nucleation of an Organic Polymorph by Ledge-Directed Epitaxy on a Molecular Crystal Substrate", S. Bonafede and M. D. Ward, J. Am. Chem. Soc., 1995, 117, 7853.

72. "Solubilization Control by Redox-Switching of Polysoaps", P. Anton, A. Laschewsky, and M. D. Ward, Polymer Bull. 1995, 34, 331.

71. "V2O5 Xerogel Films as Intercalation Hosts for Lithium I. Insertion Stoichiometry, Site Concentration and Specific Energy", H.-K. Park, W. H. Smyrl, and M. D. Ward, J. Electrochem. Soc., 142, 1995, 1068.

70. "Molecular Nanoclusters as Precursors to Conductive Thin Films and Crystals", A. C. Hillier, J. Hossick Schott, and M. D. Ward, Adv. Mater. (Research News), 1995, 7, 409.

69. "The Role of Longitudinal Waves in Quartz Crystal Microbalance Applications in Liquids", Z. Lin and M. D. Ward, Anal. Chem., 1995, 67, 685.

68. "Molecular Engineering of Crystals by Electrostatic Templating", P. J. Fagan and M. D. Ward, Perspectives in Supramolecular Chemistry, G. R. Desiraju, Ed., John Wiley, New York, 1995.

67. "Self-Assembly of Low-Dimensional Molecular Nanoclusters on Au(111) Surfaces", J. Hossick Schott and M. D. Ward, Langmuir, 1995, 11, 177.

66. "Principles and Applications of the Electrochemical Quartz Crystal Microbalance", M. D. Ward, Monographs in Electroanalytical Chemistry and Electrochemistry: Physical Electrochemistry, Principles, Methods, and Applications, I. Rubinstein, Ed., 1995, Marcel Dekker, New York.

65. "Nanoscale Imaging of Molecular Adsorption", H. Cai, A. C. Hillier, K. Franklin, C. C. Nunn, and M. D. Ward, Science, 1994, 266, 1551.

64. "Electrocrystallization of an Ordered Organic Monolayer: Selective Epitaxial Growth of b-(ET)2I3 on Graphite", A. C. Hillier, J. B. Maxson and M. D. Ward, Chem. Mater. 1994, 6, 2222.

63. "Determination of Wetting Velocities of Surfactant Superspreaders with the Quartz Crystal Microbalance", Z. Lin, R. M. Hill, H. T. Davis, and M. D. Ward, Langmuir, 1994, 10, 4060.

62. "Guanidinium para-Substituted Benzenesulfonates: Competitive Hydrogen Bonding in Layered Structures and the Design of Nonlinear Optical Materials", V. A. Russell, M. C. Etter and M. D. Ward, Chem. Mater. 1994, 6, 1206.

61. "Scanning Tunneling Microscopy of Layered Molecular Conductors", M. A. Dvorak and M. D. Ward, Chem. Mater. 1994, 6, 1386.

60. "Layered Materials by Molecular Design: Structural Enforcement by Hydrogen Bonding in Guanidinium Alkyl- and Aryl Sulfonates", V. A. Russell, M. C. Etter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 1941.

59. "Snapshots of Crystal Growth: Nanoclusters of Organic Conductors on Au(111) Surfaces", J. Hossick Schott and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 6806.

58. "Atomic Force Microscopy of the Electrochemical Nucleation and Growth of Molecular Crystals", A. Hillier and M. D. Ward, Science, 1994, 268, 1261.

57. "Directing Polymorph Selectivity During Nucleation of Anthranilic Acid on Molecular Substrates", P. W. Carter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 769.

56. "Nucleation and Growth of Molecular Crystals on Self-Assembled Monolayers", L. M. Frostman and M. D. Ward, Langmuir, 1994, 10, 576.

55. "Self-Assembled Monolayers with Charge-Transfer Groups: 16-Mercaptohexadecyl Tetrathiafulvalene Carboxylate on Gold", C. M. Yip and M. D. Ward, Langmuir, 1994, 10, 549.

54. "Nanoscale Surface Topography and Growth of Molecular Crystals: The Role of Anisotropic Intermolecular Bonding", A. Hillier, P. W. Carter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 944.

53. "Molecular Single Crystal Interfaces: Topographical Structure and Crystal Growth", P. W. Carter, A. C. Hillier and M. D. Ward, Mol. Crystal. Liq. Cryst. (Proceedings of ICCOSS XI), 1994, 242, 53.

52. "Depletion Layer Effects on the Response of the Electrochemical Quartz Crystal Microbalance", W.-W. Lee, H. S. White and M. D. Ward, Anal. Chem., 1993, 65, 3232.

51. "Topographically Directed Nucleation of Organic Crystals on Molecular Single Crystal Substrates", P. W. Carter and M. D. Ward, J. Am. Chem. Soc., 1993, 115, 11521.

50. "Synthesis and Properties of Optically Active Helical Metallocene Oligomers", T. J. Katz, A. Sudhakar, M. F. Teasley, A. M. Gilbert, W. E. Geiger, M. P. Robben, M. Wuensch and M. D. Ward, J. Am. Chem Soc. 1993, 115, 3182.

49. "Operation of an Ultrasensitive 30 MHz Quartz Crystal Microbalance in Liquids", Z. Lin, C. M. Yip, I. S. Joseph and M. D. Ward, Anal. Chem. 1993, 65, 1546.

48. "Scanning Tunneling Microscopy Studies of Organic Conductors", S. Li, H. S. White and M. D. Ward, Synthetic Metals, 1993, 55-57, 426.

47. "Real-time Measurement of Anchorage-Dependent Cell Adhesion Using a Quartz Crystal Microbalance", D. Gryte, M. D. Ward and W.-S. Hu, Biotechnol. Prog. 1993, 9, 105.

46. "Piezoelectric pH Sensors: AT-cut Quartz Resonators with Amphoteric Polymer Films", J. Wang, M. D. Ward, R. C. Ebersole and R. A. Foss, Anal. Chem. 1993, 65, 2553.

45. "Self-assembled Thiol Monolayers with Carboxylic Acid Functionality: Measuring pH-Dependent Phase Transitions with the Quartz Crystal Microbalance", J. Wang, L. M. Frostman and M. D. Ward, J. Phys. Chem. 1992, 96, 5224.

44. "Scanning Tunneling Microscopy of the Organic Semiconductor [(h5-C5Me5)2Ru(h6,h6-[22] (1,4)-cyclophane)][TCNQ]4", S. Li, H. S. White and M. D. Ward, Chem. Mater. 1992, 4, 1082.

43. "Scanning Tunneling Microscopy of the Organic Conductor (TMTSF)2X (X = ClO4-, ReO4-)", S. Li, H. S. White and M. D. Ward, J. Phys. Chem. 1992, 96, 9014.

42. "Scanning electrochemical mass sensitivity mapping of the quartz crystal microbalance in liquid media", A. C. Hillier and M. D. Ward, Anal. Chem. 1992, 64, 2539.

41. "Measurement of Interfacial Processes at Electrode Surfaces with the Electrochemical Quartz Crystal Microbalance", D. A. Buttry and M. D. Ward, Chem. Rev. (invited review), 1992, 92. 1355.

40. "Piezoelectric Cell Growth Sensor", R. C. Ebersole, R. P. Foss and M. D. Ward, Bio/. Technology, 1991, 9, 450.

39. "Radial Sensitivity of the Quartz Crystal Microbalance in Liquid Media", M. D. Ward and E. J. Delawski, Anal. Chem., 1991, 63, 886.

38. "Redox-Active Polymers by Group Transfer Polymerization: Physical, Electrochemical and Electronic Properties", A. Laschewsky and M. D. Ward, Polymer, 32, 146, 1991.

37. "Oxidation Chemistry of d0 Transition Metal Complexes", M. J. Burk, W. A. Tumas, M. D. Ward and D. R. Wheeler, J. Am. Chem. Soc., 112, 6133, 1990.

36. "Building Molecular Crystals", P. J. Fagan and M. D. Ward, Scientific American, July 1992.

35. "In-situ Interfacial Mass Measurements with Piezoelectric Transducers: Fundamentals and Applications", M. D. Ward and D. A. Buttry, Science, 249, 1000, 1990.

34. "Low Dimensional Organometallic Charge Transfer Complexes. X-Ray Structure and Magnetic Properties of a- and b-[Cr(C6Me3H3)2+][TCNQ-]", D. O'Hare, M. D. Ward and J. S. Miller, Chem. Mater. 2, 758, 1990.

33. "Electrochemical and Quartz Crystal Microbalance Evidence for Mediation and Direct Electrochemical Reactions of Small Molecules at Tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) Electrodes", M. S. Freund, A. Brajter-Toth and M. D. Ward, J. Electroanal. Chem., 289, 127, 1990.

32. "Spontaneously Formed Functionally Active Avidin Monolayers on Metal Surfaces: A Strategy for Immobilizing Biological Reagents and Design of Piezoelectric Biosensors", R. C. Ebersole, J. R. Moran and M. D. Ward, J. Am. Chem. Soc , 112, 3239, 1990.

31. "Molecular Control of Self-Assembled Monolayer Films of Imidazole-2 Thiones: Adsorption and Reactivity", A. J. Arduengo, J. R. Moran and M. D. Ward, J. Am. Chem. Soc., 112, 6153, 1990.

30. "Single-Crystal EPR Study of Triplet Excitons in [Fe(mesitylene)22+][C3(C(CN)2)3-]2", J. R. Morton, K. F. Preston, Y. Le Page, A. J. Williams and M. D. Ward, J. Chem. Phys., 93, 2222, 1990.

29. "Stuctural and Magnetic Characterization of Electron Transfer Salts of Tris(dicyanomethylene)cyclopropanide, C3[C(CN)2]3-, and Fe(C5Me5)2+ (1:1; Two Phases) and Fe(C6H3Me3)22+ (1:2), Evidence for 1-D Antiferromagnetic Behavior in Segregated [Fe(C5Me5)2+]Chains", J. S. Miller, M. D. Ward, J. H. Zhang and W. M. Reiff, Inorg. Chem., 29, 4063, 1990.

28. "Hexaazaoctadecahydrocoronene, HOC. Structural and Physical Properties of [HOC]n (n = 0, 1+, 2+, 3+, 4+)", J. S. Miller, D. A. Dixon, J. C. Calabrese, C. Vazquez, P. J. Krusic, M. D. Ward and R. L. Harlow, J. Am. Chem. Soc., 112, 381, 1990.

27. "Magnetic Coupling Relationships for Bis(Metallocene)-Benzene Complexes", J. M. Manriquez, M. D. Ward, J. C. Calabrese, P. J. Fagan, A. J. Epstein and J. S. Miller, Mol. Cryst. Liq. Cryst. 176, 527, 1989.

26. "57Fe Mossbauer Spectroscopy Studies of New Examples of Fully Averaged Mixed Valence Diiron and Iron/Ruthenium Compounds", W. M. Reiff, J. M. Manriquez, M. D. Ward and J. S. Miller, Mol. Cryst. Liq. Cryst. 176, 423, 1989.

25. "Probing Electrocrystallization of Charge Transfer Salts with the Quartz Crystal Microbalance", J. Electroanal. Chem. , 273, 79, 1989.

24. "Single Crystal EPR Spectra of Triplet Excitons in [(h5-C5Me5)Ru(h6, h6-[22](1,4)-cyclophane)Ru(h5-C5Me5)][TCNQ]4", J. R. Morton, K. F. Preston, M. D. Ward and P. J. Fagan, J. Chem. Phys., 90, 2148, 1989.

23. "Molecular Engineering of Solid State Materials:Organometallic Building Blocks", P. J. Fagan, M. D. Ward, and J. C. Calabrese, J. Am. Chem. Soc, 111, 1698, 1989.

22. "Electrostatic Structural Enforcement in Low Dimensional Solids: Synthesis, Structure and Electronic Properties of Polycationic Ruthenium Complexes with Polycyanoanions", M. D. Ward, P. J. Fagan, J. C. Calabrese and D. C. Johnson, J. Am. Chem. Soc, 111, 1719, 1989.

21. "Organometallic Donor-Acceptor Complexes with Non-Planar Donors: The Zig-Zag Linear Chain Complex [(h6-C6Me6)2M][iso-C4(CN)6] (M=Fe, Ru)", M. D. Ward and J. C. Calabrese, Organometallics, 8, 593, 1989.

20. "Electrocrystallization of Low Dimensional Solids: Directed Selectivity and Investigation of Crystal Growth with the Quartz Crystal Microbalance", M. D. Ward, Synthetic Metals, 27, B211-B218, 1988.

19. "Electrochemical Aspects of Low-Dimensional Molecular Solids", A. J. Bard, Ed., Electroanal. Chem. 161,1988.

18. "Amplified Mass Immunosorbent Assay with a Quartz Crystal Microbalance", R. C. Ebersole and M. D. Ward, J. Am. Chem. Soc, 110, 8623, 1988.

17. "Synthesis and Unusual Properties of a Helically Twisted Metallated Rubrene Derivative, P. J. Fagan, M. D. Ward, J. V. Caspar, J. C. Calabrese and P. J. Krusic, J. Am. Chem. Soc., 110, 2981, 1988.

16. "Ion Exchange of Ferro(ferricyanide) into Polyvinylferrocene Films", M. D. Ward, J. Electrochem. Soc. 135, 2747, 1988.

15. "Investigation of Open Circuit Reactions of Polymer Films Using the Quartz Crystal Microbalance. Reactions of Polyvinylferrocene Films", M. D. Ward, J. Phys. Chem, 92, 2049, 1988.

14. "Electrocrystallization, Structural and Physical Properties of Charge Transfer Complexes Derived >From [(h6-C6Me6)2M]2+ (M=Fe,Ru) and TCNQ (TCNQ = tetracyanoquinodimethane)", M. D. Ward and D. C. Johnson, Inorg. Chem. 26, 4213, 1987.

13. "Methane Photoactivation on Copper Molybdate. An Experimental and Theoretical Study", M. D. Ward, J. F. Brazdil, S. P. Mehandru and A. B. Anderson, J. Phys. Chem., 91, 6515, 1987.

12. "Investigation of Electron Transfer Processes at Open Circuit Polyvinylferrocene Films Using Rotating Ring-Disk Electrodes", M. D. Ward, J. Electroanal. Interfac. Chem., 236, 139, 1987.

11. "Characaterization of the Charge Transfer Reaction Between Decamethylferrocene and 7,7,8,8-Tetracyano-p-quinodimethane (1:1). The 57Fe Mossbauer Spectra and Structures of the Paramagnetic, Dimeric and Metamagnetic One-Dimensional Salts and the Molecular and Electronic Structures of [TCNQ]n (n =0, 1-, 2-)", J. S. Miller, J. H. Zhang, W. M. Reiff, D. A. Dixon, L. D. Preston, A. H. Reis, Jr., E. Gebert, M. Extine, J. Troup, A. J. Epstein and M. D. Ward, J. Phys. Chem., 91, 4344, 1987.

10. "Linear Chain Organometallic Donor-Acceptor Complexes and One- Dimensional Alloys. Synthesis and Structure of [(h 6-C6Me3H3)2M][C6(CN)6] (M=Fe, Ru)", M. D. Ward, Organometallics, 6,754, 1987.

9. "Electrocrystallization of Poorly Conducting Charge-Transfer Complexes", M. D. Ward, Inorg. Chem., 25, 4444, 1986.

8. "Photocatalytic Alcohol Dehydrogenation Using Ammonium Heptamolybdate", M. D. Ward, J. F. Brazdil, and R. K. Grasselli, J. Phys. Chem. 88, 4210, 1984.

7. "Electrochemical Investigation of the Energetics of Particulate Titanium Dioxide Photocatalysts. The Methyl Viologen-Acetate System", M. D. Ward, J. R. White, and A. J. Bard, J. Am. Chem. Soc., 105, 27, 1983.

6. "Photocurrent Enhancement via Trapping of Photogenerated Electrons of TiO2 Particles", M. D. Ward and A. J. Bard, J. Phys. Chem., 86, 3599, 1982.

5. "Electrophilic Chemistry of Oxide-Supported Rhodium Complexes. Activation of H-H and Alkane C-H Bonds", M. D. Ward and J. Schwartz, Organometallics, 1, 1030, 1982.

4. "Silica-Bound Rhodium Hydride Catalysts for Arene Hydogenation", M. D. Ward and J. Schwartz, J. Am. Chem. Soc., 103, 5253, 1981. 

3. "Catalytically Active Metal Oxide-Supported Rhodium Hydride Complexes", M. D. Ward and J. Schwartz, J. Mol. Catal., 11, 397, 1981.

2. "Synthesis and Partial Characterization of (Silica)rhodium Dihydrides: A New Catalyst for Olefin Hydrogenation", M. D. Ward, T. V. Harris, and J. Schwartz, J. Chem. Soc. Chem. Comm., 357, 1980.

1. "Silica-Supported Zirconium Hydrides as Isomerization or Hydrogenation Catalysts", J. Schwartz and M. D. Ward, J. Mol. Catal., 8, 465, 1980.


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