Emergent Electrochemical Phenomena at the Mesoscale
  • 1:25 p.m. March 9, 2021
  • Virtual
  • Dr. William C. Chueh
  • Associate Professor of Materials Science and Engineering; Senior Fellow at the Precourt Institute for Energy; faculty scientist at SLAC National Accelerator Laboratory
  • Stanford University

Classically, the electrode-electrolyte interface is considered the heart of electrochemistry. More recently, the use of electrochemistry to drive bulk ion insertion (e.g., Li) has powered the battery revolution. As such, electrochemical ion insertion is also extensively studied as a bulk phenomena, which also has applications in advanced computing (e.g., ionic memory devices) and dynamic tuning of functional materials (e.g., electrochromics). Bridging the length-scale gap between interfaces and bulk is the fascinating mesoscale (tens to hundreds of nanometers). It is an under-investigated length scale in electrochemistry, yet it is the length of particles, the building block of porous electrodes. In this talk, I will provide an overview of emergent electrochemical phenomena at the mesoscale, focusing on how lithium intercalation take place in a many-particle ensemble. Breakthroughs in operando microscopy techniques have led to unexpected observations such as mosaic inter-particle phase separation, metastable solid-solution and fictious phase separation. These behaviors can be rationalized by carefully considering the competition between bulk and interfacial free energy, as well as between reaction and diffusion kinetics. With these fundamental insights at hand, we can finally explain mesoscale phenomena in terms of fundamental thermodynamics and kinetics rather than in terms of unexplained heterogeneities, providing practical design rules on engineering more uniform electrochemical devices.

Seminars are open to alumni, friends of the Department, and the general public.

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